Synthesis and Characterization of Activated Carbon from Trembesi Tree Stem Biomass (Samanea Saman)
DOI:
https://doi.org/10.26555/chemica.v11i2.232Keywords:
Biomass, Trembesi charcoal, KOH activator, Surface areaAbstract
Biomass waste is currently being optimized to increase its use value and selling value on the market and reduce the impact of environmental pollution. Trembesi tree trunks (Samanea Saman) are waste that is often thrown away after being cut down. For this reason, this research has successfully utilized trembles tree trunk waste as active carbon using a KOH activator. The successful identification of active carbon synthesis was characterized using XRD, which showed an increase in crystal size from 9,902 nm to 14,207 nm. Functional group testing showed a relatively increased formation of carbon functional groups. The morphology of activated carbon shows an increase in pore size from 1537.1317 nm to 1597.3977 nm. The resulting surface area was 807,079 m2/g with an average pore size of 3.886 x 101 Å. These characterization tests provide important information for applying activated carbon on a wider scale.
References
G. W. Staples and C. R. Elevitch, “Samanea saman (rain tree),” ver 2.1: C.R. Elvitch (ed.) Species profile for Pacific Island agroforestry , Holualoa, Hawai, 2006, available: www.traditionaltree.org
A. C. Ni’am, M. Suhar, and E. Fenelon, “Characterization and potential of samanea saman-activated carbon on adsorption of copper from an aqueous solution,” Adsorption Science and Technology, vol. 2023, pp. 1–19, Aug 2023, DOI: 10.1155/2023/1911596.
L. F. Ow, S. Ghosh, and M. L. M. Yusof, “Growth of Samanea saman: Estimated cooling potential of this tree in an urban environment,” Urban For. Urban Green., vol. 41, pp. 264–271, May 2019, DOI: 10.1016/j.ufug.2019.03.021.
H. Rahardjo, F.R Harnas, I.G.B. Indrawan, E.C. Leong, P.Y. Tan, Y.K. Fong, L.F. Ow, “Understanding the stability of Samanea saman trees through tree pulling, analytical calculations and numerical models,” Urban For. Urban Green., vol. 13, no. 2, pp. 355–364, 2014, DOI: 10.1016/j.ufug.2013.12.002.
F. Fathurrahman, M. S. Nizam, W. A. Wan Juliana, F. Doni, and C. M. Z. Che Radziah, “Growth improvement of rain tree (Albizia saman Jacq. Merr) seedlings under elevated concentration of carbon dioxide (CO2),” J. Pure Appl. Microbiol., vol. 10 (3), pp. 1911–1917, Sep 2016.
K. Mosaleeyanon, S. Cha-um, and C. Kirdmanee, “Enhanced growth and photosynthesis of rain tree (Samanea saman Merr.) plantlets in vitro under a CO2-enriched condition with decreased sucrose concentrations in the medium,” Sci. Hortic., vol. 103, no. 1, pp. 51–63, Dec 2004, DOI: 10.1016/j.scienta.2004.02.010.
S. Istiana, Jumaeri, A. Tri Prasetya, “Preparasi Arang Aktif Trembesi Magnetit untuk Adsorpsi Senyawa Tannin dalam Limbah Cair,” J. Chem. Science, vol. 9, no. 1, pp. 17–23, May 2020.
A. Fitriani, J. A. Yani KM, and K. Selatan, “Perkecambahan benih trembesi (Samanea saman) Dengan Kedalaman Dan Posisi Tanam Yang Berbeda,” Jurnal Hutan Tropis, vol. 3, no. 3, pp. 222–226, Nov 2016.
A. Indriani, B. J. V Polii, and T. Ogie, “Potential leaves of trembesi (Albizia Saman (Jacq.) Merr.) as bioaccumulators for heavy metal (Pb) in Manado City,” Jurnal Agroteknologi Terapan, vol 2, no. 2, pp. 21-31, Nov 2021, DOI: 10.35791/jat.v2i2.35293.
A. Ahmad and T. Azam, “4 - Water Purification Technologies,” in Bottled and Packaged Water, Woodhead Publishing, 2019, pp. 83-120.
N. A. Negm, M. H. A. Betiha, N. M. H. El-Wakeel, and E. A. Mohamed, “An insight into recent developments in sustainable biofuel production using activated carbon catalyst produced via valorization of agricultural biomass: Challenges, and environmental prospective,” Ind. Crops Prod., vol. 209, pp. 117991, 2024, DOI: 10.1016/j.indcrop.2023.117991.
J. Wang and S. Kaskel, “KOH activation of carbon-based materials for energy storage,” J. Mater. Chem., vol. 22, no. 45, pp. 23710–23725, Oct 2012, DOI: 10.1039/C2JM34066F.
N. Mohamad Nor, L. C. Lau, K. T. Lee, and A. R. Mohamed, “Synthesis of activated carbon from lignocellulosic biomass and its applications in air pollution control - A review,” Journal of Environmental Chemical Engineering, vol 1, no. 4, pp. 658-666, Dec 2013, DOI: 10.1016/j.jece.2013.09.017.
S. Mopoung, P. Moonsri, W. Palas, and S. Khumpai, “Characterization and properties of activated carbon prepared from tamarind seeds by KOH activation for Fe(III) adsorption from aqueous solution,” Scientific World Journal, vol. 2015, no. 1, Nov 2015, DOI: 10.1155/2015/415961.
T. Tay, S. Ucar, and S. Karagöz, “Preparation and characterization of activated carbon from waste biomass,” J Hazard Mater, vol. 165, no. 1–3, pp. 481–485, Jun 2009, DOI: 10.1016/j.jhazmat.2008.10.011.
R. L. Tseng, S. K. Tseng, F. C. Wu, C. C. Hu, and C. C. Wang, “Effects of micropore development on the physicochemical properties of KOH-activated carbons,” Journal of the Chinese Institute of Chemical Engineers, vol. 39, no. 1, pp. 37–47, Apr 2008, DOI: 10.1016/j.jcice.2007.11.005.
Suhas, P. J. M. Carrott, and M. M. L. Ribeiro Carrott, “Lignin - from natural adsorbent to activated carbon: A review,” Bioresource Technology, vol 98, no. 98, pp. 2301-2312, Sep 2007, DOI: 10.1016/j.biortech.2006.08.008.
A. R. Reed and P. T. Williams, “Thermal processing of biomass natural fibre wastes by pyrolysis,” Int J Energy Res, vol. 28, no. 2, pp. 131–145, Feb. 2004, DOI: 10.1002/er.956.
T. Yang and A. C. Lua, “Characteristics of activated carbons prepared from pistachio-nut shells by physical activation,” J Colloid Interface Sci, vol. 267, no. 2, pp. 408–417, Nov 2003, DOI: 10.1016/S0021-9797(03)00689-1.
L. L. Mendame, P. Silangen, and A. Rampengan, “Perbandingan karakteristik karbon aktif arang tempurung kelapa dan arang tempurung kemiri menggunakan scanning electron microscopic dan fourier transform infrared,” JURNAL FISTA: FISIKA DAN TERAPAN, vol. 2, no. 2, pp. 105–108, Oct 2021.
L. M. Yuningsih, D. Mulyadi, and A. J. Kurnia, “Pengaruh aktivasi arang aktif dari tongkol jagung dan tempurung kelapa terhadap luas permukaan dan daya jerap iodin,” Jurnal Kimia VALENSI, vol. 2, no. 1, pp. 30–34, May 2016, DOI: 10.15408/jkv.v2i1.3091.
A. Rijali, U. Malik, and Z. J. Fisika, “pembuatan dan karakterisasi karbon aktif dari bambu betung dengan aktivasi menggunakan activating agent H2O,” JOM FMIPA, vol 2, no. 2, pp. 102-107, February 2015.